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Last Updated: 3 years ago

Possible Interaction: Nitrogen and Silicon

supplement:

Silicon

Research Papers that Mention the Interaction

Natural bond orbital (NBO) analysis, however, shows a very …-acceptor interaction between the lone pair of the nitrogen atom and the formal … orbital on the silicon and therefore, the calculations show that the Si-N bond is highly … pointing to a predominantly zwitterionic Si(+) N(-) bond in 1-4.
Chemistry  •  2014  |  View Paper
Single-crystal X-ray structure analysis revealed a Lewis acid-base interaction between the silicon and nitrogen atoms , and the obtained fluorosilylated products are silafluorene equivalents.
Angewandte Chemie  •  2014  |  View Paper
Negative regions that may be near the silicon σ-hole, arising from substituents with negative potentials, also play an important role, as they impede the approach of the nitrogen lone pair.
Journal of molecular modeling  •  2011  |  View Paper
Distances between silicon atoms and nitrogen atoms are significantly shorter than a Si-N van der Waals bond but longer than the sum of their covalent radii.
Dalton transactions  •  2010  |  View Paper