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Last Updated: 3 years ago

Possible Interaction: Molecular Oxygen and Cuprous

supplement:

Cuprous

Research Papers that Mention the Interaction

Kinetic studies document sluggish reactivity of the Cu(I) complexes with molecular oxygen and rapid rates of reduction of the Cu(II) complexes by ascorbate, indicating a remarkable stability of the Cu(I) state in all three derivatives.
Biochemistry  •  2019  |  View Paper
The Cu(I) complexes described here, in general, react slowly (within the time scale of days) with molecular oxygen , except for the ones containing the phenolic ligands 2(2+) and 5(3+) that react a bit faster.
Inorganic chemistry  •  2011  |  View Paper
The relative energies of side-… end-on binding of molecular oxygen to … supported Cu(I) species, and the singlet versus triplet nature of the ground electronic state, are sensitive to the nature … the supporting ligands and, in particular, depend upon their geometric arrangement relative to the O2 binding site.
The journal of physical chemistry. A  •  2008  |  View Paper