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Last Updated: 4 years ago

Possible Interaction: Ethanol and Cupric Cation

supplement:

Ethanol

supplement:

Cupric Cation

Research Papers that Mention the Interaction

Addition of a nucleophilic alcohol and oxidation of the Cu(II) species to Cu(III) result in rapid reductive elimination forming products and resetting the catalytic cycle.
Inorganic chemistry  •  2021  |  View Paper
Ethanol reduced mostly Cu2+ and, also, some amounts of Cu+.
Molecules  •  2020  |  View Paper
Moreover, ethanol might have acted as a reducer to induce the reduction of Cu(ii ) during synthesis.
Dalton transactions  •  2019  |  View Paper
Our data demonstrate a remarkable 10-fold exacerbation in rate of photoreduction of Cu(II ) to Cu(I) when alcohol or ether cryoprotectants are present.
The journal of physical chemistry letters  •  2018  |  View Paper