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“An exceptionally strong solvation effect of dimethyl sulfoxide (DMSO) on I 2 is identified by so far the largest observed shift of I 2 Raman peak with respect to I 2 vapor and by elongated I-I bond length in first-principles molecular-dynamics simulation.”
“The synergic action of DMSO and RuO 2 on I 2 is found to suppress the shuttle effect of redox mediator (RM) by anchoring I 2 molecules, the oxidation product of the RM.”
The Journal of organic chemistry • 2018 | View Paper
“The combination of I2 and DMSO enabled direct C-S bond formation, allowing easy and low-cost access to new functionalized C,S-tethered bisindoles and pyrrole-indole pairs with a wide diversity of substituents.”